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Molecular assembly-induced charge transfer between a mixed (phthalocyaninato)(porphyrinato) yttrium triple-decker and a fullerene

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Abstract

An interaction between a mixed (phthalocyaninato)(porphyrinato) yttrium triple-decker and a fullerene in the solution state together with the solid state is clearly revealed by 1H NMR, electronic absorption and luminescence spectroscopy, single crystal X-ray diffraction analysis results and DFT calculations. The close interface between a sandwich-type tetrapyrrole rare earth triple-decker and a fullerene in cocrystals affords stronger charge transfer (CT) and thus a more effective photoelectric conversion response than each individual.

Graphical abstract: Molecular assembly-induced charge transfer between a mixed (phthalocyaninato)(porphyrinato) yttrium triple-decker and a fullerene

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Publication details

The article was received on 13 Dec 2018, accepted on 15 Jan 2019 and first published on 15 Jan 2019


Article type: Research Article
DOI: 10.1039/C8QI01340C
Citation: Inorg. Chem. Front., 2019, Advance Article

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    Molecular assembly-induced charge transfer between a mixed (phthalocyaninato)(porphyrinato) yttrium triple-decker and a fullerene

    C. Wang, H. Wang, C. Liu, D. Qi and J. Jiang, Inorg. Chem. Front., 2019, Advance Article , DOI: 10.1039/C8QI01340C

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