Jump to main content
Jump to site search

Issue 2, 2019
Previous Article Next Article

Charge transfer and slow magnetic relaxation in a series of cyano-bridged Fe III4M II2 (M = FeII, CoII, NiII) molecules

Author affiliations

Abstract

The synthesis, single-crystal structures and magnetic properties of three new cyano-bridged complexes [FeIII4MII2] (M = FeII, CoII, NiII) are reported. Electronic absorption spectroscopy reveals the occurrence of intervalence charge transfer for [FeIII4FeII2]. Field-induced slow magnetic relaxation behavior is exhibited for [FeIII4CoII2] and [FeIII4NiII2] which originates from the ferromagnetic interactions between FeIII and MII spin centers of the square.

Graphical abstract: Charge transfer and slow magnetic relaxation in a series of cyano-bridged FeIII4MII2 (M = FeII, CoII, NiII) molecules

Back to tab navigation

Supplementary files

Publication details

The article was received on 17 Nov 2018, accepted on 21 Dec 2018 and first published on 25 Dec 2018


Article type: Research Article
DOI: 10.1039/C8QI01245H
Inorg. Chem. Front., 2019,6, 493-497

  •   Request permissions

    Charge transfer and slow magnetic relaxation in a series of cyano-bridged FeIII4MII2 (M = FeII, CoII, NiII) molecules

    J. Wang, K. R. Vignesh, J. Zhao, Z. Li and K. R. Dunbar, Inorg. Chem. Front., 2019, 6, 493
    DOI: 10.1039/C8QI01245H

Search articles by author

Spotlight

Advertisements