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Highly active copper catalyst obtained through rapid MOF decomposition

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Abstract

A decomposed copper based metal–organic framework containing amorphous Cu species was found to be a highly reactive carbon supported catalyst (a-Cu@C). This catalyst is active for reduction, oxidation, and N-arylation reactions without further tuning or optimization. Higher catalyst turnover numbers for each of these transformations are obtained when comparing a-Cu@C activity to similar Cu-based materials.

Graphical abstract: Highly active copper catalyst obtained through rapid MOF decomposition

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Publication details

The article was received on 09 Nov 2018, accepted on 02 Jan 2019 and first published on 11 Jan 2019


Article type: Research Article
DOI: 10.1039/C8QI01217B
Citation: Inorg. Chem. Front., 2019, Advance Article
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    Highly active copper catalyst obtained through rapid MOF decomposition

    A. H. T. Nguyen-Sorenson, C. M. Anderson, S. K. Balijepalli, K. A. McDonald, A. J. Matzger and K. J. Stowers, Inorg. Chem. Front., 2019, Advance Article , DOI: 10.1039/C8QI01217B

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