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Electronic effects of asymmetric and meta-alkoxy substituents on the polymerization behavior of bis-benzoxazines

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Abstract

Three isomers of benzoxazine monomers based on m-alkoxyphenol and 4,4′-methylenedianiline were synthesized and successfully isolated by column chromatography. The molecular structures of benzoxazine monomers were confirmed by proton nuclear magnetic resonance (1H NMR) and Fourier-transform infrared (FT-IR) spectroscopy. The polymerization behavior evaluated by differential scanning calorimetry (DSC) shows that the asymmetric isomer, which has a methoxy group at the 5-position and 7-positions (5,7′MO-ddm), has only one exothermic peak between temperatures of the other two symmetric isomers. The 1H NMR spectrum of monomers shows that the type and position of alkoxy groups can exert different effects on the electron density of the oxazine ring, and may result in a sensitive trend of ring-opening. The difference in electron densities was verified by the Gaussian simulation calculation results of natural charges. In this work, we provide a fundamental molecular-level understanding of the polymerization mechanism of asymmetric bis-benzoxazines, which can provide possibilities for designing new benzoxazines in order to solve the potential disadvantages of benzoxazines/polybenzoxazines and/or enhance their advantages.

Graphical abstract: Electronic effects of asymmetric and meta-alkoxy substituents on the polymerization behavior of bis-benzoxazines

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Publication details

The article was received on 31 Oct 2019, accepted on 22 Nov 2019 and first published on 22 Nov 2019


Article type: Paper
DOI: 10.1039/C9PY01641D
Polym. Chem., 2020, Advance Article

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    Electronic effects of asymmetric and meta-alkoxy substituents on the polymerization behavior of bis-benzoxazines

    Y. Lyu, E. Rachita, N. Pogharian, P. Froimowicz and H. Ishida, Polym. Chem., 2020, Advance Article , DOI: 10.1039/C9PY01641D

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