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Elucidation of the properties of discrete oligo(meth)acrylates

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Abstract

Discrete (monodisperse) methyl methacrylate (MMA) and di(ethylene glycol) ethyl ether acrylate (DEGEEA) oligomer libraries are generated via a 2-step process of RAFT polymerization and chromatographic separation. Essential thermal and physical properties such as diffusion coefficients, glass transition temperatures and melting points of the discrete oligo(MMA)s (DP 1 to 7) and oligo(DEGEEA)s (DP 1 to 10) are determined, giving insights into fundamental polymer physics in this short chain regime.

Graphical abstract: Elucidation of the properties of discrete oligo(meth)acrylates

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Publication details

The article was received on 05 Oct 2019, accepted on 19 Nov 2019 and first published on 20 Nov 2019


Article type: Communication
DOI: 10.1039/C9PY01494B
Polym. Chem., 2019, Advance Article

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    Elucidation of the properties of discrete oligo(meth)acrylates

    J. J. Haven, J. De Neve, A. Castro Villavicencio and T. Junkers, Polym. Chem., 2019, Advance Article , DOI: 10.1039/C9PY01494B

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