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Issue 48, 2019
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A facile approach to thermomechanically enhanced fatty acid-containing bioplastics using metal–ligand coordination

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Abstract

Biomass-based polymers show promise for the mitigation of environmental issues associated with petroleum-derived commodity polymers; however, due to poor entanglement, many of these polymers typically lack mechanical strength and toughness. Herein, we report a facile approach to utilizing metal–ligand coordination to create physical crosslinking, and thus chain entanglements for plant oil-derived polymers. A series of soybean oil-derived copolymers containing a pendant acid group can be easily synthesized using free radical polymerization. The resulting chain architecture can be controlled through supramolecular interactions to produce bioplastics with enhanced thermomechanical properties. The metal–ligand coordination in this work can be varied by changing the metal lability and the density of metal–ligand bonds, allowing for further control of properties. The final bioplastics remain reprocessable and feature good thermoplastic and stimuli-responsive properties.

Graphical abstract: A facile approach to thermomechanically enhanced fatty acid-containing bioplastics using metal–ligand coordination

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Supplementary files

Article information


Submitted
01 Oct 2019
Accepted
10 Nov 2019
First published
11 Nov 2019

Polym. Chem., 2019,10, 6570-6579
Article type
Paper
Author version available

A facile approach to thermomechanically enhanced fatty acid-containing bioplastics using metal–ligand coordination

M. E. Lamm, L. Song, Z. Wang, B. Lamm, L. Fu and C. Tang, Polym. Chem., 2019, 10, 6570
DOI: 10.1039/C9PY01479A

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