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Issue 48, 2019
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A double-site Lewis pair for highly active and living synthesis of sulfur-containing polymers

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Abstract

This work describes an organic double-site Lewis pair with exceedingly high activity for the copolymerization of carbonyl sulfide (COS) with propylene oxide (PO). Fully alternating poly(monothiocarbonate)s can be produced with >99% regioregularity in a living manner. Molecular weight of the copolymers can be tuned in the range of 3.8–103.1 kg mol−1 (PDI: 1.09–1.18). Importantly, the on–off character of this system was also investigated and proved to be an effective way to regulate the copolymerization and synthesize block copolymers.

Graphical abstract: A double-site Lewis pair for highly active and living synthesis of sulfur-containing polymers

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Publication details

The article was received on 11 Sep 2019, accepted on 15 Nov 2019 and first published on 15 Nov 2019


Article type: Communication
DOI: 10.1039/C9PY01371G
Polym. Chem., 2019,10, 6555-6560

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    A double-site Lewis pair for highly active and living synthesis of sulfur-containing polymers

    J. Yang, H. Wang, L. Hu, X. Hong and X. Zhang, Polym. Chem., 2019, 10, 6555
    DOI: 10.1039/C9PY01371G

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