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Issue 32, 2019
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Photo-induced copper-RDRP in continuous flow without external deoxygenation

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Abstract

Photo-induced Cu-RDRP of acrylates in a continuous flow reactor without the need for deoxygenation or externally added reagents. Optimization of the catalyst concentration and the flow rate/residence time leads to well-defined polyacrylates with controlled molecular weights, excellent initiator efficiency, high end-group fidelity polymers and product uniformity. A multifunctional initiator was also used to demonstrate the versatility of the system.

Graphical abstract: Photo-induced copper-RDRP in continuous flow without external deoxygenation

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Supplementary files

Article information


Submitted
27 Jun 2019
Accepted
06 Jul 2019
First published
19 Jul 2019

This article is Open Access

Polym. Chem., 2019,10, 4402-4406
Article type
Communication

Photo-induced copper-RDRP in continuous flow without external deoxygenation

A. Marathianos, E. Liarou, A. Anastasaki, R. Whitfield, M. Laurel, A. M. Wemyss and D. M. Haddleton, Polym. Chem., 2019, 10, 4402
DOI: 10.1039/C9PY00945K

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