Manqing Xie, Chen Wu, Chongyi Chen, Ying Liu and Chuanzhuang Zhao
Polym. Chem., 2019,10, 4852-4858
DOI:
10.1039/C9PY00851A,
Paper
A novel shape memory hydrogel with photo-adaptable permanent shape has been developed on the basis of alginate–Ca2+ coordination and the host–guest interaction between α-cyclodextrin and azobenzene. The reversible nature of alginate–Ca2+ confers the hydrogel with functions such as shape memory and shape recovery, and the light-responsive transition of azobenzene could be applied to generate a new permanent shape by tuning the host–guest complexation via UV light.