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Radical polymerization of ‘dehydroaspirin’ with the formation of a hemiacetal ester skeleton: a hint for recyclable vinyl polymers

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Abstract

A vinyl polymer with a cyclic hemiacetal ester skeleton was synthesized via the radical polymerization of 2-methylene-4H-benzo[d][1,3]dioxin-4-one (MBDO; so-called ‘dehydroaspirin’). This material could be decomposed to acetic acid and salicylic acid (the raw ingredients for MBDO) by acid hydrolysis, and thus has potential as a recyclable vinyl polymer.

Graphical abstract: Radical polymerization of ‘dehydroaspirin’ with the formation of a hemiacetal ester skeleton: a hint for recyclable vinyl polymers

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Publication details

The article was received on 29 Mar 2019, accepted on 01 May 2019 and first published on 07 May 2019


Article type: Communication
DOI: 10.1039/C9PY00474B
Polym. Chem., 2019, Advance Article

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    Radical polymerization of ‘dehydroaspirin’ with the formation of a hemiacetal ester skeleton: a hint for recyclable vinyl polymers

    A. Kazama and Y. Kohsaka, Polym. Chem., 2019, Advance Article , DOI: 10.1039/C9PY00474B

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