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Issue 5, 2019
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A simple and versatile route to amphiphilic polymethacrylates: catalytic chain transfer polymerisation (CCTP) coupled with post-polymerisation modifications

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Abstract

Amphiphilic polymers have become key figures in the fields of pharmacology, medicine, agriculture and cosmetics. The use of reversible deactivation radical polymerisation (RDRP) techniques has allowed advances in the synthesis of amphiphilic polymers. However, the high price to performance ratio of these methods can limit their industrial application. Herein, poly(glycidyl methacrylate) polymers of varying molecular weights were first synthesised by catalytic chain transfer polymerisation (CCTP). Amphiphilic polymers were then prepared using a simple one-pot, post-polymerisation modification process involving Michael-thiol addition in the presence of a range of hydrophobic mercaptans, followed by ring-opening of the epoxide groups with ethanolamine using microwave-assisted synthesis. This procedure allows for the synthesis of fully functional polymers within 3 hours. A range of well-defined materials are prepared and characterised by GPC, NMR, FTIR, DLS, TGA, and TEM.

Graphical abstract: A simple and versatile route to amphiphilic polymethacrylates: catalytic chain transfer polymerisation (CCTP) coupled with post-polymerisation modifications

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Supplementary files

Article information


Submitted
19 Nov 2018
Accepted
03 Jan 2019
First published
03 Jan 2019

This article is Open Access

Polym. Chem., 2019,10, 646-655
Article type
Paper

A simple and versatile route to amphiphilic polymethacrylates: catalytic chain transfer polymerisation (CCTP) coupled with post-polymerisation modifications

C. J. Atkins, G. Patias, J. S. Town, A. M. Wemyss, A. M. Eissa, A. Shegiwal and D. M. Haddleton, Polym. Chem., 2019, 10, 646
DOI: 10.1039/C8PY01641K

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