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Quasi-monodisperse polymer libraries via flash column chromatography: correlating dispersity with glass transition

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Abstract

Quasi-monodisperse (Đ = 1.005–1.040) poly(methyl acrylate) (PMA) polymer libraries are obtained via flash column chromatography separation of polydisperse (Đ = 1.130) PMA made from reversible addition–fragmentation chain transfer (RAFT) polymerization. The limits of chromatographic polymer separation and analysis are discussed. In addition, the influence of dispersity on the thermal properties (glass transition) of the PMA library is investigated.

Graphical abstract: Quasi-monodisperse polymer libraries via flash column chromatography: correlating dispersity with glass transition

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Publication details

The article was received on 13 Nov 2018, accepted on 27 Dec 2018 and first published on 28 Dec 2018


Article type: Communication
DOI: 10.1039/C8PY01603H
Citation: Polym. Chem., 2019, Advance Article
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    Quasi-monodisperse polymer libraries via flash column chromatography: correlating dispersity with glass transition

    J. J. Haven and T. Junkers, Polym. Chem., 2019, Advance Article , DOI: 10.1039/C8PY01603H

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