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Facile synthesis of conjugated microporous polymer-based porphyrin units for adsorption of CO2 and organic vapors

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Abstract

We present two novel porphyrin (Porp)-based conjugated microporous polymers (CMPs; Porp-TPE-CMP and Porp-Py-CMP), formed via an FeCl3-catalyzed cross-coupling reaction between pyrrole and aromatic aldehyde. The resultant CMPs exhibited high CO2 selectivity compared with N2 and CH4, and good capacity for organic vapors.

Graphical abstract: Facile synthesis of conjugated microporous polymer-based porphyrin units for adsorption of CO2 and organic vapors

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Publication details

The article was received on 16 Oct 2018, accepted on 21 Dec 2018 and first published on 10 Jan 2019


Article type: Communication
DOI: 10.1039/C8PY01476K
Citation: Polym. Chem., 2019, Advance Article
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    Facile synthesis of conjugated microporous polymer-based porphyrin units for adsorption of CO2 and organic vapors

    Y. Xu, D. Cui, S. Zhang, G. Xu and Z. Su, Polym. Chem., 2019, Advance Article , DOI: 10.1039/C8PY01476K

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