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Functional polyamides with gem-diazido units: synthesis and diversification

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Abstract

A diazidated malonate derivative was employed as a monomer for the reagent-free one-pot synthesis of several polyamides containing geminal diazido moieties within the polymer backbone. Using different diamines, azide-rich polyamides with diverse properties and sensitivities dependent on the structure of the diamine units were obtained. Postpolymerization CuAAC reactions of the geminal diazido units in the polymer backbone allowed for the introduction of additional functionalities, and the construction of densely functionalized polymeric structures.

Graphical abstract: Functional polyamides with gem-diazido units: synthesis and diversification

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Publication details

The article was received on 24 Jul 2018, accepted on 04 Nov 2018 and first published on 09 Nov 2018


Article type: Communication
DOI: 10.1039/C8PY01087K
Citation: Polym. Chem., 2019, Advance Article
  • Open access: Creative Commons BY license
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    Functional polyamides with gem-diazido units: synthesis and diversification

    P. Biallas, J. Heider and S. F. Kirsch, Polym. Chem., 2019, Advance Article , DOI: 10.1039/C8PY01087K

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