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Rhodium(III)-catalyzed unreactive C(sp3)–H alkenylation of N-alkyl-1H-pyrazoles with alkynes

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Abstract

The first example of pyrazole-directed rhodium(III)-catalyzed unreactive C(sp3)–H alkenylation with alkynes has been described, which showed a relatively broad substrate scope with good functional group compatibility. Moreover, we demonstrated that the transitive coordinating center pyrazole could be easily removed under mild conditions.

Graphical abstract: Rhodium(iii)-catalyzed unreactive C(sp3)–H alkenylation of N-alkyl-1H-pyrazoles with alkynes

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Publication details

The article was received on 10 Jul 2019, accepted on 30 Jul 2019 and first published on 30 Jul 2019


Article type: Communication
DOI: 10.1039/C9OB01531K
Org. Biomol. Chem., 2019, Advance Article

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    Rhodium(III)-catalyzed unreactive C(sp3)–H alkenylation of N-alkyl-1H-pyrazoles with alkynes

    T. Li, C. Liu, S. Wu, C. Chen and B. Zhu, Org. Biomol. Chem., 2019, Advance Article , DOI: 10.1039/C9OB01531K

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