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Recently, missing pieces of organophosphorus compounds, i.e., aromatic-fused diketophosphanyl compounds, have attracted much attention as promising scaffolds of building blocks for functional organic materials. In this review, the brief historical background, synthetic methods, structures, and optoelectronic aspects of aromatic-fused diketophosphanyls are overviewed.

Graphical abstract: Aromatic-fused diketophosphanyl-core organic functional materials: phosphorus mimics of imides or beyond?

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