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Issue 25, 2019
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meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-N-methyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization

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Abstract

A concise and convenient synthetic methodology leading to an unambiguous isolation of two hitherto unknown highly stable single conformers of meso-aryl substituted unorthodox 5,10-porphodimethenes has been developed by the inclusion of N-methyl pyrrole units with α,β and β,β-linkages into the core of heterocyclic macrocycles.

Graphical abstract: meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-N-methyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization

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Article information


Submitted
08 May 2019
Accepted
31 May 2019
First published
31 May 2019

Org. Biomol. Chem., 2019,17, 6131-6135
Article type
Communication

meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-N-methyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization

N. Halder, M. Sangeetha, D. Usharani and H. Rath, Org. Biomol. Chem., 2019, 17, 6131
DOI: 10.1039/C9OB01062A

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