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Palladium-Catalyzed Carbonylative Synthesis of Substituted Cyclopentenones from Aryl Iodides and Internal Alkynes

Abstract

In this communcation, a palladium-catalyzed carbonylative synthesis of substituted cyclopentenones has been developed. With aryl iodides and internal alkynes as the substrates, via domino process consisted by formal Pauson-Khand reaction, good yields of the desired products were obtained. Interestingly, formic acid has been used both as hydrogen and carbon monoxide sources in this system.

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Publication details

The article was received on 03 May 2019, accepted on 16 May 2019 and first published on 16 May 2019


Article type: Communication
DOI: 10.1039/C9OB01019J
Org. Biomol. Chem., 2019, Accepted Manuscript

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    Palladium-Catalyzed Carbonylative Synthesis of Substituted Cyclopentenones from Aryl Iodides and Internal Alkynes

    X. Wu, J. Peng and W. Wang, Org. Biomol. Chem., 2019, Accepted Manuscript , DOI: 10.1039/C9OB01019J

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