Issue 24, 2019
From the journal:

Organic & Biomolecular Chemistry

(Hetero)arylboration of alkynes: a strategy for the synthesis of α,α-bis(hetero)arylketones†

Yuan Huang,a   Allison M. Bergmanna  and  M. Kevin Brown ORCID logo *a  

* Corresponding authors

a Indiana University, Department of Chemistry, 800 E. Kirkwood Ave., Bloomington, IN 47401, USA
E-mail: brownmkb@indiana.edu

Abstract

A method for (hetero)arylboration of alkynes is presented. The reaction allows for the synthesis of densely functionalized tetrasubstituted alkenes with control of regioselectivity and diastereoselectivity. The conversion of the products to the corresponding α,α-bis(hetero)arylketones is also shown.

Graphical abstract: (Hetero)arylboration of alkynes: a strategy for the synthesis of α,α-bis(hetero)arylketones

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Article information

DOI
https://doi.org/10.1039/C9OB00961B
Article type
Communication
Submitted
26 Apr 2019
Accepted
28 May 2019
First published
05 Jun 2019

Org. Biomol. Chem., 2019,17, 5913-5915

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(Hetero)arylboration of alkynes: a strategy for the synthesis of α,α-bis(hetero)arylketones

Y. Huang, A. M. Bergmann and M. K. Brown, Org. Biomol. Chem., 2019, 17, 5913 DOI: 10.1039/C9OB00961B

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