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Issue 20, 2019
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Unidirectional complexation of pillar[4]arene[1]benzoquinoneoxime with alkyl alcohols

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Abstract

Despite progress in the unidirectional complexation of cyclodextrins and calixarenes with nonsymmetric guests, unidirectional complexation using pillararenes as hosts remains scarcely explored. In this report, we describe the formation of unidirectional [2]pseudorotaxane-like complexes which were realized using n-alkyl alcohol guests and pillar[4]arene[1]benzoquinoneoxime made from pillar[4]arene[1]quinone in a selective monofunctionalizing manner.

Graphical abstract: Unidirectional complexation of pillar[4]arene[1]benzoquinoneoxime with alkyl alcohols

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Article information


Submitted
22 Mar 2019
Accepted
24 Apr 2019
First published
24 Apr 2019

Org. Biomol. Chem., 2019,17, 4975-4978
Article type
Communication

Unidirectional complexation of pillar[4]arene[1]benzoquinoneoxime with alkyl alcohols

K. Li, Z. Wang, C. Xie, T. Chen, H. Qiang, Y. A. Liu, X. Jia, W. Hu and K. Wen, Org. Biomol. Chem., 2019, 17, 4975
DOI: 10.1039/C9OB00665F

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