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Issue 17, 2019
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Deoxygenative cross-electrophile coupling of benzyl chloroformates with aryl iodides

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Abstract

This work describes Ni-catalyzed cross-electrophile coupling of benzyl chloroformate derivatives with aryl iodides that generates a wide range of diaryl methane products. The mild reaction conditions merit the C–O bond radical fragmentation of benzyl chloroformates via halide abstraction or a single electron reduction by a Ni catalyst. This work offers a new substrate type for cross-electrophile couplings.

Graphical abstract: Deoxygenative cross-electrophile coupling of benzyl chloroformates with aryl iodides

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Publication details

The article was received on 18 Mar 2019, accepted on 28 Mar 2019 and first published on 28 Mar 2019


Article type: Communication
DOI: 10.1039/C9OB00628A
Citation: Org. Biomol. Chem., 2019,17, 4230-4233

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    Deoxygenative cross-electrophile coupling of benzyl chloroformates with aryl iodides

    Y. Pan, Y. Gong, Y. Song, W. Tong and H. Gong, Org. Biomol. Chem., 2019, 17, 4230
    DOI: 10.1039/C9OB00628A

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