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Issue 10, 2019
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Indium- and zinc-catalyzed enantioselective amide propargylation of aldehydes with stannylated allenyl amides

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Abstract

The catalytic enantioselective propargylation of aldehydes with newly prepared stannyl allenyl amides is described. The reaction has been accomplished by using catalytic amounts of indium chloride, zinc chloride, and a chiral BINOL derivative, affording amide-functionalized homopropargyl alcohols in excellent yields and enantioselectivities.

Graphical abstract: Indium- and zinc-catalyzed enantioselective amide propargylation of aldehydes with stannylated allenyl amides

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Publication details

The article was received on 08 Jan 2019, accepted on 07 Feb 2019 and first published on 07 Feb 2019


Article type: Communication
DOI: 10.1039/C9OB00040B
Citation: Org. Biomol. Chem., 2019,17, 2614-2618

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    Indium- and zinc-catalyzed enantioselective amide propargylation of aldehydes with stannylated allenyl amides

    T. Sengoku, I. Ikeda, K. Ai, M. Takahashi and H. Yoda, Org. Biomol. Chem., 2019, 17, 2614
    DOI: 10.1039/C9OB00040B

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