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Issue 3, 2019
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A photocatalytic sp3 C–S, C–Se and C–B bond formation through C–C bond cleavage of cycloketone oxime esters

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Abstract

The photocatalytic thiolation, selenylation and borylation of cycloketone oxime esters through iminyl radical-triggered C–C bond cleavage were described. The reactions provide a unified approach to alkyl sulfur, selenium and boron compounds tethered to a synthetically useful nitrile group.

Graphical abstract: A photocatalytic sp3 C–S, C–Se and C–B bond formation through C–C bond cleavage of cycloketone oxime esters

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Publication details

The article was received on 30 Nov 2018, accepted on 14 Dec 2018 and first published on 14 Dec 2018


Article type: Paper
DOI: 10.1039/C8OB02987C
Citation: Org. Biomol. Chem., 2019,17, 533-540

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    A photocatalytic sp3 C–S, C–Se and C–B bond formation through C–C bond cleavage of cycloketone oxime esters

    D. Anand, Y. He, L. Li and L. Zhou, Org. Biomol. Chem., 2019, 17, 533
    DOI: 10.1039/C8OB02987C

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