Issue 3, 2019

A photocatalytic sp3 C–S, C–Se and C–B bond formation through C–C bond cleavage of cycloketone oxime esters

Abstract

The photocatalytic thiolation, selenylation and borylation of cycloketone oxime esters through iminyl radical-triggered C–C bond cleavage were described. The reactions provide a unified approach to alkyl sulfur, selenium and boron compounds tethered to a synthetically useful nitrile group.

Graphical abstract: A photocatalytic sp3 C–S, C–Se and C–B bond formation through C–C bond cleavage of cycloketone oxime esters

Supplementary files

Article information

Article type
Paper
Submitted
30 Nov 2018
Accepted
14 Dec 2018
First published
14 Dec 2018

Org. Biomol. Chem., 2019,17, 533-540

A photocatalytic sp3 C–S, C–Se and C–B bond formation through C–C bond cleavage of cycloketone oxime esters

D. Anand, Y. He, L. Li and L. Zhou, Org. Biomol. Chem., 2019, 17, 533 DOI: 10.1039/C8OB02987C

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