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Issue 3, 2019
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Platinum(II)-catalyzed selective para C–H alkoxylation of arylamines through a coordinating activation strategy

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Abstract

A highly efficient method to selectively install alkoxy onto the para position of arylamines via a coordinating activation strategy has been reported. Various substrates are compatible, providing the corresponding products in good to excellent yields. This strategy gives an efficient and practical solution for the synthesis of unsymmetrical aryl ethers. A free radical pathway mechanism is advised for transformation.

Graphical abstract: Platinum(ii)-catalyzed selective para C–H alkoxylation of arylamines through a coordinating activation strategy

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Publication details

The article was received on 26 Nov 2018, accepted on 12 Dec 2018 and first published on 14 Dec 2018


Article type: Paper
DOI: 10.1039/C8OB02942C
Citation: Org. Biomol. Chem., 2019,17, 490-497
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    Platinum(II)-catalyzed selective para C–H alkoxylation of arylamines through a coordinating activation strategy

    J. Shen, J. Xu, H. Cai, C. Shen and P. Zhang, Org. Biomol. Chem., 2019, 17, 490
    DOI: 10.1039/C8OB02942C

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