Jump to main content
Jump to site search

Issue 7, 2019
Previous Article Next Article

Palladium-catalyzed salt-free double decarboxylative aryl allylation

Author affiliations

Abstract

This report describes a palladium-catalyzed decarboxylative aryl allylation between unactivated benzoic acids and allylic carbonates. This transformation successfully couples a variety of carbonates and benzoic acids in good yield (up to 94%) using 1 mol% palladium. This salt free allyl-arylation proceeds without added base, copper, or silver. The only stoichiometric byproducts are carbon dioxide and tert-butanol.

Graphical abstract: Palladium-catalyzed salt-free double decarboxylative aryl allylation

  • This article is part of the themed collection: New Talent
Back to tab navigation

Supplementary files

Publication details

The article was received on 26 Jul 2018, accepted on 15 Aug 2018 and first published on 15 Aug 2018


Article type: Communication
DOI: 10.1039/C8OB01806E
Citation: Org. Biomol. Chem., 2019,17, 1709-1713

  •   Request permissions

    Palladium-catalyzed salt-free double decarboxylative aryl allylation

    R. A. Daley and J. J. Topczewski, Org. Biomol. Chem., 2019, 17, 1709
    DOI: 10.1039/C8OB01806E

Search articles by author

Spotlight

Advertisements