Jump to main content
Jump to site search


Self-templated synthesis of Co3O4 hierarchical nanosheets from a metal-organic framework for efficient visible-light photocatalytic CO2 reduction

Abstract

Efficient photocatalytic conversion of CO2 into energy-rich chemicals is of great significance for both environmental conservation and alleviating energy crisis. However, convenient synthesis of low-cost, durable and eco-friendly photocatalysts with novel morphology or structure for highly selective photocatalytic CO2 reduction remains a challenge. Herein, Co3O4 hierarchical nanosheets were synthesized by calcination of a novel cobalt metal-organic framework (MOF) nanosheets prepared by a facile oil bath method. In such Co MOF nanosheets, 1,4-naphthalenedicarboxylic acid was chosen as the organic linker, rather than the commonly used 2-methylimidazole for ZIF-67. After thermal treatment in air, the obtained Co3O4 inherited the 2D morphology of its MOF template and evolved into hierarchical nanosheets which were composed of small nanoparticles. Benefiting from large surface area, abundant mesoporous structure as well as good capability towards the separation and transfer of photo-generated charge carriers induced by less interior oxygen vacancies, the Co3O4 hierarchical nanosheets showed a CO generation rate of 39.70 μmol h-1 in visible-light photocatalytic CO2 reduction, which was superior than Co3O4 nanoparticles and commercial Co3O4. What’s more, a CO selectivity of 77.3 % was achieved, which is among the highest within cobalt-based spinel oxide photocatalysts for CO2 conversion.

Back to tab navigation

Supplementary files

Publication details

The article was accepted on 16 Nov 2019 and first published on 18 Nov 2019


Article type: Paper
DOI: 10.1039/C9NR08669B
Nanoscale, 2019, Accepted Manuscript

  •   Request permissions

    Self-templated synthesis of Co3O4 hierarchical nanosheets from a metal-organic framework for efficient visible-light photocatalytic CO2 reduction

    J. Ren, Y. Zheng, K. Yuan, L. Zhou, K. Wu and Y. Zhang, Nanoscale, 2019, Accepted Manuscript , DOI: 10.1039/C9NR08669B

Search articles by author

Spotlight

Advertisements