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Frustrated Lewis Pairs Photocatalyst for Visible Light-Driven Reduction of CO into Multi-Carbon Chemicals

Abstract

Photocatalytic reduction of carbon monoxide (CO), an increasingly available and low-cost feedstock that could benefit from CO2 reduction, into high value-added multi-carbon chemicals, is significant for desirable carbon cycling, as well as high efficiency conversion and high density storage of solar energy. However, developing low cost but highly active photocatalysts with long-term stability for CO coupling and reduction remains a great challenge. Herein, by density functional theory (DFT) computations and taking advantage of the frustrated Lewis pairs (FLPs) concept, we identified a complex consisting of single boron (B) atom decorated on the optically active C2N monolayer (i.e., B/C2N) as an efficient and stable photocatalyst for CO reduction. On the designed B/C2N catalyst, CO can be efficiently reduced into ethylene (C2H4) and propylene (C3H6) with free energy increase of 0.22 eV for the potential-determining step, which greatly benefits from the pull-push function of the B-N FLPs composed of the decorating B and the host N atoms. Moreover, the newly designed B/C2N catalyst shows significant visible light absorption with suitable band positions for CO reduction into C2H4 and C3H6. All these unique features render the B/C2N photocatalyst as an ideal candidate for visible light driven CO reduction into high value-added multi-carbon fuels and chemicals.

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Publication details

The article was received on 02 Sep 2019, accepted on 09 Oct 2019 and first published on 10 Oct 2019


Article type: Paper
DOI: 10.1039/C9NR07559C
Nanoscale, 2019, Accepted Manuscript

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    Frustrated Lewis Pairs Photocatalyst for Visible Light-Driven Reduction of CO into Multi-Carbon Chemicals

    Z. Chen, J. Zhao, J. Zhao, Z. Chen and L. Yin, Nanoscale, 2019, Accepted Manuscript , DOI: 10.1039/C9NR07559C

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