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Quasi-hydrophilic black silicon photocathodes with inverted pyramid arrays for enhanced hydrogen generation

Abstract

Micro-/nanostructured silicon (Si) photoelectrodes are promising for efficient solar-driven water splitting. In this work, an elaborate study on textured Si photocathodes is reported. Compared to conventional textured Si photocathodes, the well-designed Si photocathode with randomly-distributed inverted pyramid arrays (SiIPs) generates a larger photovoltage of 440 mV for its higher effective minority carrier density, and produces a higher photocurrent density at a high reverse bias voltage due to its quasi-hydrophilicity. With the help of cobalt disulfide (CoS2) nanocrystals, sluggish charge kinetics of SiIPs photocathodes can be further improved. The optimal SiIPs/CoS2 photocathode yields an onset potential of 0.22 V vs. reversible hydrogen electrode (RHE) and a saturated photocurrent density of 10.4 mA·cm-2 at -0.45 V (vs. RHE). Besides, this cathode produces a stable photocurrent density of ~6.60 mA·cm-2 at 0 V (vs. RHE) for 12000 s in acidic media. Notably, our work presents a facile and inexpensive method to fabricate efficient Si photoelectrodes, which may promote the evolution of textured Si-based electrodes for potential photoelectrochemical and photocatalytic applications.

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Supplementary files

Publication details

The article was received on 02 Aug 2019, accepted on 15 Nov 2019 and first published on 16 Nov 2019


Article type: Paper
DOI: 10.1039/C9NR06635G
Nanoscale, 2019, Accepted Manuscript

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    Quasi-hydrophilic black silicon photocathodes with inverted pyramid arrays for enhanced hydrogen generation

    S. Zhao, 袁. Yuan, Q. Wang, W. Liu, R. Wang and S. Yang, Nanoscale, 2019, Accepted Manuscript , DOI: 10.1039/C9NR06635G

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