Jump to main content
Jump to site search

Issue 35, 2019
Previous Article Next Article

Tuning the catalytic activity and selectivity of water-soluble bimetallic RuPt nanoparticles by modifying their surface metal distribution

Author affiliations

Abstract

Bimetallic ruthenium–platinum nanoparticles (RuPt NPs) of different surface distributions and stabilized by using a sulfonated N-heterocyclic carbene ligand (1-(2,6-diisopropylphenyl)-3-(3-potassium sulfonatopropyl)-imidazol-2-ylidene) were prepared from Ru(COD)(COT) (COD = cyclooctadiene and COT = cyclooctatriene), and platinum precursors having various decomposition rates (Pt(NBE)3, NBE = norbornene, Pt(CH3)2(COD) and Pt2(DBA)3, DBA = dibenzylideneacetone). Structural and surface studies by FT-IR and solid-state MAS NMR, using carbon monoxide as a probe molecule, revealed the presence of different structures and surface compositions for different nanoparticles of similar sizes, which principally depend on the decomposition rate of the organometallic precursors used during the synthesis. Specifically, the slower the decomposition rate of the platinum precursor, the higher the number of Pt atoms at the NP surface. The different bimetallic RuPt NPs, as well as their monometallic equivalents (Pt and Ru NPs), were used in isotopic H/D exchange through C–H activation on L-lysine. Interestingly, the activity and selectivity of the direct C–H deuteration were dependent on the NP surface composition at the α position but not on that at the ε position. Chemical shift perturbation (CSP) experiments revealed that the difference in reactivity at the α position is due to a Pt–carboxylate interaction, which hinders the H/D exchange.

Graphical abstract: Tuning the catalytic activity and selectivity of water-soluble bimetallic RuPt nanoparticles by modifying their surface metal distribution

Back to tab navigation

Supplementary files

Article information


Submitted
15 May 2019
Accepted
29 Jul 2019
First published
30 Jul 2019

Nanoscale, 2019,11, 16544-16552
Article type
Paper

Tuning the catalytic activity and selectivity of water-soluble bimetallic RuPt nanoparticles by modifying their surface metal distribution

D. Bouzouita, G. Lippens, E. A. Baquero, P. F. Fazzini, G. Pieters, Y. Coppel, P. Lecante, S. Tricard, L. M. Martínez-Prieto and B. Chaudret, Nanoscale, 2019, 11, 16544
DOI: 10.1039/C9NR04149D

Social activity

Search articles by author

Spotlight

Advertisements