Making Prussian blue analogues nanoparticles luminescent: effect of the luminophore confinement over the properties

Ekaterina Mamontova; Jérôme Long; Rute A. S. Ferreira; Alexandre M. P. Botas; Fabrice Salles; Yannick Guari; Luis D. Carlos; Joulia Larionova

doi:10.1039/C8NR09982K

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Making Prussian blue analogues nanoparticles luminescent: effect of the luminophore confinement over the properties†

Ekaterina Mamontova,

^a Jérôme Long,

*^a Rute A. S. Ferreira,

^b Alexandre M. P. Botas,

^b Fabrice Salles,

^c Yannick Guari,

^a Luis D. Carlos

^b and Joulia Larionova

Author affiliations

* Corresponding authors

^a Institut Charles Gerhardt, UMR 5253, Equipe Ingénierie Moléculaire et Nano-Objets, Université de Montpellier, ENSCM, CNRS, Place Eugène Bataillon, 34095 Montpellier Cedex 5, France
E-mail: jerome.long@umontpellier.fr

^b Department of Physics and CICECO Aveiro - Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal

^c Institut Charles Gerhardt Montpellier, UMR 5253, Equipe Agrégats, Interfaces et Matériaux pour l'Energie ENSCM/CNRS/UM, Place Eugène Bataillon, 34095 Montpellier Cedex 5, France

Abstract

In this communication, we report the post-synthetic functionalization of K⁺/Ni²⁺/[Cr(CN)₆]³⁻ Prussian blue analogue (PBA) nanoparticles by the 2-aminoanthracene luminophore to yield a bifunctional magneto-luminescent nanosystem. The photoluminescence properties of the fluorophore are found modified by the confinement effect upon adsorption, while the magnetic behavior of PBA is preserved.

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Article information

DOI: https://doi.org/10.1039/C8NR09982K
Article type: Communication
Submitted: 10 Dec 2018
Accepted: 19 Jan 2019
First published: 21 Jan 2019

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Nanoscale, 2019,11, 7097-7101

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Making Prussian blue analogues nanoparticles luminescent: effect of the luminophore confinement over the properties

E. Mamontova, J. Long, R. A. S. Ferreira, A. M. P. Botas, F. Salles, Y. Guari, L. D. Carlos and J. Larionova, Nanoscale, 2019, 11, 7097 DOI: 10.1039/C8NR09982K

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Making Prussian blue analogues nanoparticles luminescent: effect of the luminophore confinement over the properties†

Abstract

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Making Prussian blue analogues nanoparticles luminescent: effect of the luminophore confinement over the properties

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