Er3+-to-Yb3+ and Pr3+-to-Yb3+ energy transfer for highly efficient near-infrared cryogenic optical temperature sensing†
Here, the very high thermal sensing capability of Er3+,Yb3+ doped LaF3 nanoparticles, where Er3+-to-Yb3+ energy transfer is used, is reported. Also Pr3+,Yb3+ doped LaF3 nanoparticles, with Pr3+-to-Yb3+ energy transfer, showed temperature sensing in the same temperature regime, but with lower performance. The investigated Er3+,Yb3+ doped LaF3 nanoparticles show a remarkably high relative sensitivity Sr of up to 6.6092% K−1 (at 15 K) in the near-infrared (NIR) region, in the cryogenic (15–105 K) temperature region opening a whole new thermometric system suitable for advanced applications in the very low temperature ranges. To date reports on NIR cryogenic sensors have been very scarce.
- This article is part of the themed collection: International Year of the Periodic Table : Lanthanides for Precision Therapy and Beyond