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Novel liquid crystalline organogelators based on terephthalic acid derivatives: Properties and promotion through the formation of halogen bonding

Abstract

Terephthalic acid-based aromatic amides A1 and A2 and an aromatic Schiff base SB are synthesized, allowing a stable gelation with numerous types of organic solvents. Moreover, A2 and SB are liquid crystals with a good mesomorphic temperature domain. The three compounds are halogen bonding (XB) acceptors and form stable XB with 1,4-diiodotetrafluorobenzene (DIB), as proven through Fourier transform infrared spectroscopy (FTIR), A2 1H nuclear magnetic resonance titration, and a single crystal X-ray analysis of the cocrystal formed through the control compound A2-OMe with DIB. The formation of XB significantly promotes the gelling abilities of A1 and A2, improves the thermal stability of SB, and affects the mesomorphic properties of A2 and SB to a certain degree. Gels formed using A2 or A2-DIB exhibit the selective sensing of Cu2+ over Zn2+, Mg2+, and Hg2+. Scanning electron microscopy, X-ray diffraction, FTIR, polarized optical microscopy, and differential scanning calorimetry are used to study the structures of the gels and mesophases.

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Publication details

The article was received on 21 Nov 2019, accepted on 02 Dec 2019 and first published on 03 Dec 2019


Article type: Paper
DOI: 10.1039/C9NJ05811G
New J. Chem., 2019, Accepted Manuscript

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    Novel liquid crystalline organogelators based on terephthalic acid derivatives: Properties and promotion through the formation of halogen bonding

    Y. Huang, X. Zhang, W. Cui, X. Wang, B. Li, Y. Zhang and J. Yang, New J. Chem., 2019, Accepted Manuscript , DOI: 10.1039/C9NJ05811G

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