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First representatives of functionalized D–π–A chromophores containing a tunable hydroxytricyanopyrrole (HTCP) acceptor and N,N-disubstituted aminophenyl donor

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Abstract

The first representatives of D–π–A chromophores containing a hydroxytricyanopyrrole (HTCP) acceptor and N,N-disubstituted aminophenyl donor were synthesized. The obtained molecules include reactive NH- and OH-fragments allowing the photophysical properties of the chromophores to be tuned, which is not possible for the well-known chromophores of the tricyanofuran (TCF) and tricyanopyrrole (TCP) series. The absorption properties of the synthesized HTCP-chromophores with a p-aminophenyl electron donor substituent were thoroughly studied.

Graphical abstract: First representatives of functionalized D–π–A chromophores containing a tunable hydroxytricyanopyrrole (HTCP) acceptor and N,N-disubstituted aminophenyl donor

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Publication details

The article was received on 25 Sep 2019, accepted on 28 Oct 2019 and first published on 29 Oct 2019


Article type: Letter
DOI: 10.1039/C9NJ04874J
New J. Chem., 2019, Advance Article

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    First representatives of functionalized D–π–A chromophores containing a tunable hydroxytricyanopyrrole (HTCP) acceptor and N,N-disubstituted aminophenyl donor

    S. V. Fedoseev, M. Yu. Belikov, M. Yu. Ievlev and O. V. Ershov, New J. Chem., 2019, Advance Article , DOI: 10.1039/C9NJ04874J

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