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One-pot synthesis of benzotripyrrole derivatives from 1H-pyrroles

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Abstract

Herein, we report, for the first time, the synthesis of C3h symmetric benzotripyrroles having unprotected pyrrolic nitrogens in a single step from a known starting material, i.e. 2-methyl-1H-pyrrole-3-carboxylates, and characterized the isolated intermediate compounds to elucidate the mechanism. Further, computational studies were performed to probe the dual descriptor and aromaticity to understand the reactivity of the pyrrole derivatives towards cyclization and the stability of the benzotripyrrole.

Graphical abstract: One-pot synthesis of benzotripyrrole derivatives from 1H-pyrroles

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Publication details

The article was received on 13 Sep 2019, accepted on 28 Oct 2019 and first published on 29 Oct 2019


Article type: Letter
DOI: 10.1039/C9NJ04700J
New J. Chem., 2019, Advance Article

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    One-pot synthesis of benzotripyrrole derivatives from 1H-pyrroles

    O. Pandeeti, S. K. Bijigiri and P. K. Panda, New J. Chem., 2019, Advance Article , DOI: 10.1039/C9NJ04700J

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