Jump to main content
Jump to site search


A novel 3D Cd-based luminescent coordination polymer for selective sensing of 4-NP and NZF

Author affiliations

Abstract

A novel 3D luminescent coordination polymer (LCP), {[Cd3.53-OH)(TCPB)2(bimb)(H2O)3]·0.5 dioxane·0.5 H2O}n (1) (H3TCPB = 1,3,5-tris(4-carbonylphenyloxy)benzene, bimb = 1,4-bis(imidazol-1-ylmethyl)benene), has been synthesized using solvothermal methods, and characterized by single-crystal X-ray diffraction analysis, elemental analyses, IR spectroscopy, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analysis. Furthermore, luminescence experiments showed that 1 can act as a sensor towards trace NACs and antibiotics in aqueous solution with high sensitivity and selectivity. Moreover, the luminescence quenching mechanisms of 1 are mainly attributed to photo-induced electron transfer (PET) and resonance energy transfer (RET) between host and guest molecules.

Graphical abstract: A novel 3D Cd-based luminescent coordination polymer for selective sensing of 4-NP and NZF

Back to tab navigation

Supplementary files

Publication details

The article was received on 16 Aug 2019, accepted on 01 Oct 2019 and first published on 03 Oct 2019


Article type: Paper
DOI: 10.1039/C9NJ04250D
New J. Chem., 2019, Advance Article

  •   Request permissions

    A novel 3D Cd-based luminescent coordination polymer for selective sensing of 4-NP and NZF

    J. Zhang, L. Gao, Y. Wang, L. Zhai, X. Niu and T. Hu, New J. Chem., 2019, Advance Article , DOI: 10.1039/C9NJ04250D

Search articles by author

Spotlight

Advertisements