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Visible-light-promoted organic dye-catalyzed sulfidation and phosphorylation of arylhydrazines toward aromatic sulfides and diarylphosphoryl hydrazides

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Abstract

Visible-light-promoted sulfidation and phosphorylation of arylhydrazines for the synthesis of aromatic sulfides and diarylphosphoryl hydrazides were developed using the organic dyes rose bengal and Na2-eosin Y as photocatalysts, respectively. This strategy offers an efficient and mild transition-metal-free synthetic protocol for the formation of C–S and N–P bonds from arylhydrazines.

Graphical abstract: Visible-light-promoted organic dye-catalyzed sulfidation and phosphorylation of arylhydrazines toward aromatic sulfides and diarylphosphoryl hydrazides

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Publication details

The article was received on 16 Jul 2019, accepted on 04 Aug 2019 and first published on 05 Aug 2019


Article type: Paper
DOI: 10.1039/C9NJ03692J
New J. Chem., 2019, Advance Article

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    Visible-light-promoted organic dye-catalyzed sulfidation and phosphorylation of arylhydrazines toward aromatic sulfides and diarylphosphoryl hydrazides

    R. Li, T. Shi, X. Chen, Q. Lv, Y. Zhang, Y. Peng, L. Qu and B. Yu, New J. Chem., 2019, Advance Article , DOI: 10.1039/C9NJ03692J

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