Jump to main content
Jump to site search

Issue 41, 2019
Previous Article Next Article

Functionalization of [Re6Q8(CN)6]4− clusters by methylation of cyanide ligands

Author affiliations

Abstract

Methylation of anionic cluster complexes [Re6Q8(CN)6]4− with ((CH3)3O)BF4 or CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8(CH3NC)6]2+ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, 1H NMR, 13C NMR, 14N NMR, 15N NMR, 77Se NMR, and 125Te NMR techniques, electrochemistry, TGA, and photophysical measurements.

Graphical abstract: Functionalization of [Re6Q8(CN)6]4− clusters by methylation of cyanide ligands

Back to tab navigation

Supplementary files

Publication details

The article was received on 07 Jun 2019, accepted on 10 Sep 2019 and first published on 11 Sep 2019


Article type: Paper
DOI: 10.1039/C9NJ02971K
New J. Chem., 2019,43, 16338-16348

  •   Request permissions

    Functionalization of [Re6Q8(CN)6]4− clusters by methylation of cyanide ligands

    M. A. Mikhaylov, A. D. Mironova, K. A. Brylev, T. S. Sukhikh, I. V. Eltsov, D. V. Stass, A. L. Gushchin, N. Kitamura and M. N. Sokolov, New J. Chem., 2019, 43, 16338
    DOI: 10.1039/C9NJ02971K

Search articles by author

Spotlight

Advertisements