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Electrochemistry-related aspects of safety of graphene-based non-aqueous electrochemical supercapacitors: a case study with MgO-decorated few-layer graphene as an electrode material

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Abstract

Herein, electrochemistry-related aspects of safety of graphene-based non-aqueous electrochemical supercapacitors are elucidated by using MgO-decorated few-layer graphene (FLG) as an electrode material. MgO-decorated FLG (MgO/FLG) is chosen in this study because on the one hand it has good physical characteristics making it lucrative as an electrode material in graphene based aqueous and non-aqueous electrochemical supercapacitors and on the other hand in MgO/FLG, MgO is chemically bonded to FLG (through either oxygen-mediation (Mg–O–C) or direct bonding with carbon (Mg–C)) and thereby reduces the possibility of exothermic reactions upon charge–discharge cycling leading to an unsafe failure of the supercapacitor. As anticipated, coin cell supercapacitors fabricated with MgO/FLG symmetric electrodes and a non-aqueous BMIM BF4 electrolyte popped up exothermically (the temperature rise was in the range of 110–165 °C) during the initial charge cycles. Post-cycling X-ray photoelectron spectroscopic analysis of the electrode material revealed that the chemical bonding between MgO and FLG triggered highly exothermic reactions leading to the formation of products such as MgF2 and Mg(OH)2. This study elucidates that the heat production and the gaseous species release during charging–discharging cycles are serious safety concerns if the choice of the electrode material and non-aqueous electrolyte (BMIM BF4 and plausibly PF6 based electrolytes) combination is not properly made. On the other hand when MgO/FLG was used in combination with a 6 M KOH aqueous electrolyte in an aqueous supercapacitor, it delivered a discharge capacitance as high as 168 F g−1 at a current density of 0.5 A g−1. Even at the end of the 5000th cycle with a current rate of 3 A g−1, a discharge capacitance of 101 F g−1 corresponding to 95% retention was recorded.

Graphical abstract: Electrochemistry-related aspects of safety of graphene-based non-aqueous electrochemical supercapacitors: a case study with MgO-decorated few-layer graphene as an electrode material

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Publication details

The article was received on 24 Feb 2019, accepted on 28 Apr 2019 and first published on 06 May 2019


Article type: Paper
DOI: 10.1039/C9NJ00991D
New J. Chem., 2019, Advance Article

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    Electrochemistry-related aspects of safety of graphene-based non-aqueous electrochemical supercapacitors: a case study with MgO-decorated few-layer graphene as an electrode material

    S. Petnikota, V. V. S. S. Srikanth, J. J. Toh, M. Srinivasan, C. V. R. Bobba, S. Adams and M. V. Reddy, New J. Chem., 2019, Advance Article , DOI: 10.1039/C9NJ00991D

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