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Organoselenium Small Molecules as Catalysts for Oxidative Functionalization of Organic Molecules

Abstract

Although the fact that organoselenium chemistry has become an exciting topic in synthetic chemistry and pharmaceuticals from the last few decades. Usually, organoselenium molecules as reagents have only recently been developed in epoxidation or halogenation of olefins by using peroxides and dihalogens or halogenating reagents, respectively. Early few years, there are some reports are available but these are not a clear vision for catalytic use of organoselenium molecules and although important breakthroughs, they signify just the very preliminary stages of a nascent field. This perspective highlights the critical analysis of the challenges that lead to the development of organoselenium compounds and their use as a versatile catalyst in organic synthesis towards oxidation of olefins and C–H bonds in past one decade. Furthermore, the emphasis here differs from previous reviews of the field by classifying the various types of catalysis and the diverse strategies employed not only for oxidation of olefins but also carbon-hydrogen bond for carbon-carbon and carbon-heteroatom bond formation for the synthesis of various heterocyclic molecules by asymmetric indication.

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Publication details

The article was received on 22 Feb 2019, accepted on 29 Apr 2019 and first published on 30 Apr 2019


Article type: Perspective
DOI: 10.1039/C9NJ00964G
New J. Chem., 2019, Accepted Manuscript

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    Organoselenium Small Molecules as Catalysts for Oxidative Functionalization of Organic Molecules

    V. Rathore, C. Jose and S. KUMAR, New J. Chem., 2019, Accepted Manuscript , DOI: 10.1039/C9NJ00964G

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