Jump to main content
Jump to site search


Di-tert-butylcatecholate derivatives of titanocene

Author affiliations

Abstract

Reaction of Cp2TiCl2 (Cp = η5-C5H5) with sodium 3,6-di-tert-butylcatecholate (Na2Cat36) leads to mononuclear complex [Cp2TiCat36], while the isomeric sodium 3,5-di-tert-butylcatecholate (Na2Cat35) gives the mixed-valence binuclear complex [Cp2Ti(μ-Cat35)2TiCp]. The latter was characterized by EPR spectroscopy and magnetic susceptibility measurements, and shown to be a Ti-centred radical. DFT calculations confirm that the unpaired electron is located on the Ti atom from the TiCp2 fragment.

Graphical abstract: Di-tert-butylcatecholate derivatives of titanocene

Back to tab navigation

Supplementary files

Publication details

The article was received on 13 Feb 2019, accepted on 26 Mar 2019 and first published on 27 Mar 2019


Article type: Paper
DOI: 10.1039/C9NJ00771G
Citation: New J. Chem., 2019, Advance Article

  •   Request permissions

    Di-tert-butylcatecholate derivatives of titanocene

    P. A. Petrov, T. S. Sukhikh, V. A. Nadolinny, A. S. Bogomyakov, Y. A. Laricheva and A. V. Piskunov, New J. Chem., 2019, Advance Article , DOI: 10.1039/C9NJ00771G

Search articles by author

Spotlight

Advertisements