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Issue 13, 2019
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A direct comparison of monomeric vs. dimeric and non-annulated vs. N-annulated perylene diimide electron acceptors for organic photovoltaics

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Abstract

Herein we report on four perylene diimide (PDI) variants to study the effects that N-annulation and dimerization have on optoelectronic properties and organic solar cell device performance. The PDI compounds were synthesized following a scalable and efficient procedure and studied by cyclic voltammetry, solution and solid-state optical absorption spectroscopy, emission spectroscopy, and density functional theory analysis. The thin-film morphology was probed by optical and atomic force microscopy. Dimerization stabilized the frontier molecular orbital energy levels and reduced aggregation in the thin-films. N-Annulation resulted in a destabilization of the frontier molecular orbital energy levels in both the monomers and dimers and enabled the formation of smoother films with smaller domain sizes. Each PDI molecule was evaluated as a non-fullerene acceptor in bulk-heterojunction solar cells using the donor polymers PTB7-Th and PffBT4T-2OD. The dimers outperformed the monomers, while N-annulated PDIs led to devices with higher open-circuit voltages.

Graphical abstract: A direct comparison of monomeric vs. dimeric and non-annulated vs. N-annulated perylene diimide electron acceptors for organic photovoltaics

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Publication details

The article was received on 24 Dec 2018, accepted on 02 Mar 2019 and first published on 07 Mar 2019


Article type: Paper
DOI: 10.1039/C8NJ06491A
New J. Chem., 2019,43, 5187-5195

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    A direct comparison of monomeric vs. dimeric and non-annulated vs. N-annulated perylene diimide electron acceptors for organic photovoltaics

    M. Nazari, E. Cieplechowicz, T. A. Welsh and G. C. Welch, New J. Chem., 2019, 43, 5187
    DOI: 10.1039/C8NJ06491A

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