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Issue 9, 2019
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The first enantioselective strategy towards speciosins

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Abstract

Speciosins constitute a group of natural compounds that have never been synthesized enantioselectively. We propose to introduce chirality by the use of enantiopure 3-halo-cis-1,2-cyclohexadienediols of microbial origin. The introduction of the alkynylic side chain by Sonogashira's methodology was successful, thus confirming a valuable strategy for the asymmetric preparation of speciosins.

Graphical abstract: The first enantioselective strategy towards speciosins

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Publication details

The article was received on 05 Dec 2018, accepted on 31 Jan 2019 and first published on 01 Feb 2019


Article type: Letter
DOI: 10.1039/C8NJ06158K
Citation: New J. Chem., 2019,43, 3653-3655

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    The first enantioselective strategy towards speciosins

    A. Peixoto de Abreu Lima, L. Suescun, E. Pandolfi and V. Schapiro, New J. Chem., 2019, 43, 3653
    DOI: 10.1039/C8NJ06158K

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