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Study of duo functional behaviour of 1,2-bis (4-bromobenzamide) benzene by synchronous fluorescence spectroscopy

Abstract

This study presents the duo functionality of 1,2-bis (4-bromobenzamide) benzene, where depending on stoichiometric conditions, temperature and reaction time, the compound may act as a PdCl2 ligand or as one of the reagents of the Suzuki coupling reaction. This duo functional behaviour was confirmed in the catalytic reactions which were monitored by synchronous fluorescence spectroscopy. Based on the results, the reaction is a versatile system, since the bisamide can act at different stages of the coupling mechanism and collaborates with the principle of green chemistry once mild reaction conditions and non-toxic solvents were used.

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Publication details

The article was received on 29 Nov 2018, accepted on 03 Apr 2019 and first published on 05 Apr 2019


Article type: Paper
DOI: 10.1039/C8NJ06066E
Citation: New J. Chem., 2019, Accepted Manuscript

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    Study of duo functional behaviour of 1,2-bis (4-bromobenzamide) benzene by synchronous fluorescence spectroscopy

    S. M. Nobre, V. M.S Cavalheiro and F. Kessler, New J. Chem., 2019, Accepted Manuscript , DOI: 10.1039/C8NJ06066E

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