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Issue 3, 2019
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Electrochemically driven P–H oxidation and functionalization: synthesis of carbamoylphosphonates from phosphoramides and alcohols

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Abstract

An electrochemical method to achieve carbamoylphosphonates from phosphoramides and alcohols via P–H oxidation and functionalization by using n-Bu4NI as a catalyst is reported. A series of carbamoylphosphonates were obtained with good to excellent yields under mild reaction conditions. The electrochemical reaction is carried out under constant current electrolysis, with the alcohol being used as a solvent and a substrate, and is an attractive green synthesis method.

Graphical abstract: Electrochemically driven P–H oxidation and functionalization: synthesis of carbamoylphosphonates from phosphoramides and alcohols

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Publication details

The article was received on 12 Nov 2018, accepted on 10 Dec 2018 and first published on 11 Dec 2018


Article type: Paper
DOI: 10.1039/C8NJ05739G
Citation: New J. Chem., 2019,43, 1531-1535
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    Electrochemically driven P–H oxidation and functionalization: synthesis of carbamoylphosphonates from phosphoramides and alcohols

    Q. Wu, X. Chen, C. Huo, X. Wang and Z. Quan, New J. Chem., 2019, 43, 1531
    DOI: 10.1039/C8NJ05739G

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