Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 3, 2019
Previous Article Next Article

Electrochemically driven P–H oxidation and functionalization: synthesis of carbamoylphosphonates from phosphoramides and alcohols

Author affiliations

Abstract

An electrochemical method to achieve carbamoylphosphonates from phosphoramides and alcohols via P–H oxidation and functionalization by using n-Bu4NI as a catalyst is reported. A series of carbamoylphosphonates were obtained with good to excellent yields under mild reaction conditions. The electrochemical reaction is carried out under constant current electrolysis, with the alcohol being used as a solvent and a substrate, and is an attractive green synthesis method.

Graphical abstract: Electrochemically driven P–H oxidation and functionalization: synthesis of carbamoylphosphonates from phosphoramides and alcohols

Back to tab navigation

Supplementary files

Publication details

The article was received on 12 Nov 2018, accepted on 10 Dec 2018 and first published on 11 Dec 2018


Article type: Paper
DOI: 10.1039/C8NJ05739G
Citation: New J. Chem., 2019,43, 1531-1535

  •   Request permissions

    Electrochemically driven P–H oxidation and functionalization: synthesis of carbamoylphosphonates from phosphoramides and alcohols

    Q. Wu, X. Chen, C. Huo, X. Wang and Z. Quan, New J. Chem., 2019, 43, 1531
    DOI: 10.1039/C8NJ05739G

Search articles by author

Spotlight

Advertisements