Imidazolium-based ionic liquids as stabilizers for electrode modification with water-soluble porphyrin

Abstract

The water-soluble porphyrin, known as 5,10,15,20-tetrakis(1-methyl-4-pyridyl)porphyrin (TMPyP), was successfully stabilized onto a carbon paste electrode (CP) by covering up the TMPyP-modified surface with a layer of ionic liquid (IL), particularly 1-butyl-3-methyl imidazolium hexafluorophosphate (BMim PF₆) or 1-butyl-3-methyl imidazolium bis(trifluoromethylsulfonyl)imide (BMim NTf₂). Noncovalent interactions established between TMPyP and ILs combined with the hydrophobicity of the latter yielded a new class of modified electrodes, denoted as CP/TMPyP/IL. These new systems exhibited higher electroactive areas as compared to those of CP and CP/IL electrodes, as well as a stable and reproducible electrochemical behavior in aqueous solutions. The obtained CP/TMPyP/BMim PF₆ and CP/TMPyP/BMim NTf₂ electrodes were used as electrochemical sensors for nitrite oxidation. The positive results showed that these electrodes can be considered as an alternative for nitrite detection in the concentration range under investigation.