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Direct synthesis of 8-acylated quinoline N-oxides via palladium-catalyzed selective C–H activation and C(sp2)–C(sp2) cleavage

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Abstract

An efficient method for the synthesis of 8-acylated quinoline N-oxides from the reaction of quinoline N-oxides with α-diketones via C–C bond cleavage was developed. A variety of quinoline N-oxides and α-diketones with different groups was well tolerated in this system.

Graphical abstract: Direct synthesis of 8-acylated quinoline N-oxides via palladium-catalyzed selective C–H activation and C(sp2)–C(sp2) cleavage

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Publication details

The article was received on 23 Oct 2018, accepted on 20 Dec 2018 and first published on 21 Dec 2018


Article type: Letter
DOI: 10.1039/C8NJ05374J
Citation: New J. Chem., 2019, Advance Article
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    Direct synthesis of 8-acylated quinoline N-oxides via palladium-catalyzed selective C–H activation and C(sp2)–C(sp2) cleavage

    G. Li, D. Dong, X. Yu and Z. Wang, New J. Chem., 2019, Advance Article , DOI: 10.1039/C8NJ05374J

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