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Synthesis of pyrrolidinium-based plastic crystals exhibiting high ionic conductivity at ambient temperature

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Abstract

In this work, pyrrolidinium-based OIPCs were synthesised together with various anionic species to investigate the effect of the anion structure on the OIPC properties. In particular, the relationship between the ionic conductivity and ionic radius ratio (ρ) of the anion and cation was investigated. The results suggested that OIPCs with a smaller ρ value were found to exhibit a higher ionic conductivity.

Graphical abstract: Synthesis of pyrrolidinium-based plastic crystals exhibiting high ionic conductivity at ambient temperature

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Publication details

The article was received on 09 Oct 2018, accepted on 24 Jan 2019 and first published on 25 Jan 2019


Article type: Letter
DOI: 10.1039/C8NJ05127E
Citation: New J. Chem., 2019, Advance Article

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    Synthesis of pyrrolidinium-based plastic crystals exhibiting high ionic conductivity at ambient temperature

    S. Yamaguchi, H. Yamada, Y. Takeoka, M. Rikukawa and M. Yoshizawa-Fujita, New J. Chem., 2019, Advance Article , DOI: 10.1039/C8NJ05127E

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