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Issue 3, 2019
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An efficient heterogeneous copper fluorapatite (CuFAP)-catalysed oxidative synthesis of diaryl sulfone under mild ligand- and base-free conditions

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Abstract

A simple, eco-friendly and efficient method for the synthesis of unsymmetrical diaryl sulfones using heterogeneous copper fluorapatite (CuFAP)-catalysed coupling of aryl sulfonic acid and phenyl boronic acid has been developed with good to excellent yields without use of any ligand, base or co-catalyst. Broad substrate scope and gram scale operations are the important features of this method.

Graphical abstract: An efficient heterogeneous copper fluorapatite (CuFAP)-catalysed oxidative synthesis of diaryl sulfone under mild ligand- and base-free conditions

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Publication details

The article was received on 24 Sep 2018, accepted on 10 Dec 2018 and first published on 11 Dec 2018


Article type: Paper
DOI: 10.1039/C8NJ04845B
Citation: New J. Chem., 2019,43, 1632-1636
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    An efficient heterogeneous copper fluorapatite (CuFAP)-catalysed oxidative synthesis of diaryl sulfone under mild ligand- and base-free conditions

    R. B. Kamble, S. S. Chavan and G. Suryavanshi, New J. Chem., 2019, 43, 1632
    DOI: 10.1039/C8NJ04845B

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