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Anomalous polarization switching and permanent retention in a ferroelectric ionic conductor

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Abstract

Ferroelectricity features the electrical switching of off-centered ions between the potential double well of the non-centrosymmetric lattice, while ionic conduction requires long-range hopping of ions across the lattice periodic potentials. The two seemingly mutually exclusive phenomena become strongly intertwined at the nanoscale in electrochemically active materials. However, the intrinsic coupling between ferroelectric switching and ionic activities in bulk crystalline materials remains largely unexplored. Here, we report anomalous polarization switching characteristics of a van der Waals (vdW) layered ferroelectric ionic conductor, CuInP2S6. By synergistic polarization switching and dielectric spectroscopy studies in both temperature and frequency domains, we reveal that the polarization switching kinetics of this compound is ionic-conduction-limited, due to the strong electrostatic interaction between ferroelectric and ionic defect dipoles. The crucial role of thermally-activated displacive instability of Cu ions is confirmed by the single-crystal X-ray crystallography results. The findings provide fundamental insight into the ionic kinetics under an electric field in crystals with coexisting dipole order (ferroelectricity) and disorder (ionic defect and conductivity). Last but not least, we demonstrate that the spontaneous ionic defect-polarization interlock can lead to permanent ferroelectric retention, which is essential for information storage.

Graphical abstract: Anomalous polarization switching and permanent retention in a ferroelectric ionic conductor

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Publication details

The article was received on 05 Aug 2019, accepted on 10 Sep 2019 and first published on 11 Sep 2019


Article type: Communication
DOI: 10.1039/C9MH01215J
Mater. Horiz., 2019, Advance Article

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    Anomalous polarization switching and permanent retention in a ferroelectric ionic conductor

    S. Zhou, L. You, A. Chaturvedi, S. A. Morris, J. S. Herrin, N. Zhang, A. Abdelsamie, Y. Hu, J. Chen, Y. Zhou, S. Dong and J. Wang, Mater. Horiz., 2019, Advance Article , DOI: 10.1039/C9MH01215J

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